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LITHIUM
Here in
the states we constantly hear about Lithium. It's lighter,
stronger, more powerful, no memory and smaller.
The voltages with Li-on range in multiples of 3.7. Thus you will
see, 3.7 -7.4 - 11.2. Really futuristic techno-poop
terminology abounds but there is a dark
side and Darth Vader is well represented here.
Here in the
states we are in the 6v-12v theology
(cars are twelve, most emergency lights are six) which has
existed for decades and was based on 2 volts per cell as used in
Sealed Lead Acid. Sort of the standard of the industry.
This will change as Lithium gets more prolific. That's as
long as Lithium doesn't continue to blowup plants, pickup trucks and
DELL, APPLE Toshiba, and Matsushita aka Panasonic, and IBM laptop computers
can handle the economic loses.
There are several types of Lithium and we could write a book about
the variants. (So off to the Wikipedia on-line encyclopedia,
it's a long item. For me it saves typing).
NEW FEDERAL AIRLINE REGULATIONS AS TO LITHIUM SPARE BATTERIES.
Effective January 1, 2008, the following
rules apply to the spare lithium batteries you carry with
you in case the battery in a device runs low: Here are
some Points of Lightning. The problem is Lithium is a
fire and explosive hazard. It's hard to fight a fire below
decks in the cargo area, It's easier to contain in the cabin
of an aircraft. Loose Lithium's if jarred or the
terminals compromised will burn, oxidize or explode.
- Spare batteries
are the batteries you carry separately from the devices
they power.
- When batteries are installed in a
device, they are not considered spare
batteries.
- You may not
pack a spare lithium battery in your checked
baggage.
- You may
bring spare lithium batteries with you in
CARRY ON BAGGAGE if you pack them properly. Use your
smarts.
- Even though we recommend carrying
your devices with you in carry-on baggage as well, if you
must bring one in checked baggage, you may
check it with the batteries installed.
- Removing batteries from devices does
not enhance safety! When they are in the device they are
intended for they are supported by it's design.
- Keep batteries in their original
packaging. This packaging is specifically designed to
protect batteries in transportation, at the store, and in
your home or worksite.
- If original packaging is
unavailable, tape over the electrical connections
(contacts or terminals) Electrical tape is great for this
job, but any adhesive tape not made of metallic material
will do!
- Placing each battery in its own
individual plastic bag will also isolate the battery's
terminals
- Every rechargeable battery-powered
device comes with a charger that is right for that device.
They do not interchange.
FROM WIKIPEDIA:
The term "lithium battery" refers to a family of different
chemistries, comprising many types of cathodes and electrolytes. One
type of lithium cell having a large energy density is the
lithium-thionyl chloride cell. In this cell, a liquid mixture of
thionyl chloride and lithium tetrachloroaluminate acts as the
cathode and electrolyte respectively. A porous carbon material
serves as a anode current collector which receives electrons from
the external circuit. However, lithium-thionyl chloride batteries
are generally not sold to the consumer market, and find more use in
commercial/industrial applications, or are installed
into devices where no consumer replacement is performed.
Lithium-thionyl chloride batteries are well suited to extremely
low-current applications where long life is necessary, e.g. wireless
alarm systems.
The most common type of lithium cells
used in consumer applications uses metallic lithium as anode and
manganese dioxide as cathode, with a salt of lithium dissolved in an
organic solvent
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The Lithium batteries constructed of Lithium -Ion
carry warnings about placing in fire. Li-on can ignite if
exposed to air. In 1995, an entire SONY plant blew up in Japan
so problems with Li-On are not new to SONY. Toshiba was also
involved. It is reported
this latest foo-pah will cost about 430 million dollars which has
since doubled.
-
ADD throwing on the ground to fire cautions. IF the small
controller internally should break the battery will short and may
explode. People walk in our local battery store and pitch the
dead ones on the counter. Boom.
-
A gentleman in South Korea made the papers when his cell phone went
off in his ear. He no longer resides on earth.
-
In the 80's Lithium EPIRBS (ELT's in those days) were recalled from
aircraft as they leaked and corroded control cables!) Buying cheap
Lithium batteries are a stupid thing to do.
-
Lithium batteries find application
in many long-life, critical devices, such as artificial pacemakers
and other implantable electronic medical devices. These devices use
specialized lithium-iodide batteries designed to last 15 or more
years.
-
Lithium batteries can be used in
place of ordinary alkaline cells in many devices, such as clocks and
cameras. Although they are more costly, lithium cells will provide
much longer life, thereby minimizing battery replacement. However,
attention must be given to the higher voltage developed by the
lithium cells before using them as a drop-in replacement in devices
that normally use ordinary cells.
-
Small lithium batteries are very
commonly used in small, portable electronic devices, such as PDAs,
watches, thermometers, and calculators, as backup batteries in
computers and communication equipment, and in remote car locks. They
are available in many shapes and sizes, with a common variety being
the 3 volt "coin" type manganese variety, typically 20 mm in
diameter and 1.6–4 mm thick. The heavy electrical demands of many of
these devices make lithium batteries a particularly attractive
option. In particular, lithium batteries can easily support the
brief, heavy current demands of devices such as digital cameras, and
they maintain a higher voltage for a longer period than alkaline
cells.
-
Lithium batteries can provide extremely high
currents and can discharge very rapidly when short-circuited.
Although this is useful in applications where high currents are
required, a too-rapid discharge of a lithium battery can result in
overheating of the battery, rupture, and even explosion.
Lithium-thionyl chloride batteries are particularly capable of this
type of discharge. Consumer batteries usually incorporate
over-current or thermal protection or vents in order to prevent
explosion.
- Because of the above risks, shipping
and carriage of lithium batteries is restricted in some
situations, particularly transport of lithium batteries by
air. Read the new regulations mandatory January 1, 2008 at
the top of the page.
- The computer industry's drive to
increase battery capacity can test the limits of sensitive
components such as the membrane separator, a polyethylene or
polypropylene film that is only 20-25 µm thick. The energy
density of lithium-ion batteries has more than doubled since
they were introduced in 1991. When the battery has more and
more material, the separator can undergo stress. In
French, this translates as "Mon ami, sacre bleu, Oui de
poop-e-doo". In English, "Oh Shit".
- Unused lithium batteries provide a
convenient source of lithium metal for use as a reducing
agent in illegal methamphetamine labs. Some jurisdictions
have passed laws to restrict lithium battery sales or asked
businesses to make voluntary restrictions in an attempt to
help curb the creation of illegal meth labs. On the
good side, hopefully if there are explosions, a meth lab is
a real good place for it to happen.
For example a
newspaper article from January 2004 reports that Wal-Mart
stores limit the sale of disposable lithium batteries to
three packages in Missouri and four packages in other
states. However, the heavy demand for lithium
batteries for use in modern, current-hungry devices such as
digital cameras conflicts with such restrictions.
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