THE BATTERY TRUTH PAGE

INTRODUCTION:
• A battery pack is a group of identical batteries or individual battery cells that are linked.
• Because they are individual cells they may be configured in several ways to attain a certain operational voltage
• Series, parallel or a combination of the two to attain either higher voltage or longer drain times.
• Basically in its's design stage, the voltage, capacity, or power density is determined by the devices needs.
THE PARTS:
• The individual batteries or cells.
• The interconnects which provide electrical conductivity between the cells and are made of a highly refined metal with very little resistance.
• Rechargeable battery packs of Ni-MH, Ni-Cad usually have a temperature sensor which indicates the end of charging. Thus we know heat is a factor in charging, discharging and failure as heat ruins any electronics in close quarters.
• Interconnects are those bright tabs connecting the batteries. They are welded, not soldered in commercial packs for reasons of continuity, consistency, and speed, welding being a lot faster than hand soldering. The weld, usually "double tapped" connects each cell in positive to negative to create chains.
• Sometimes batteries are arranged as in most flashlights as series strings. Inline cells are selected stacked with solder, slight pressure is applied, current pulse generates heat to solder them together and to weld all connections internal to the cell.
• Another method is making a very thin v-shaped tab, welding and flipping the battery into position and covering it with shrink tubing.
IT GETS COMPLEX:
• Ever wonder why some battery chargers cost $300.00 and others cost $29.95.? Packs with multiple cells might be regulated or controlled so that the peak voltage of each battery or cell is kept below its maximum value.
This allows weaker batteries in the string to charge better allowing a more balanced pack. A well-balanced pack lasts longer and delivers better performance so it is a rather beneficial component of high capacity or expensive packs.
This is why you match batteries for use. The better professional chargers have this capability, the cheaper ones are merely averaging and don't add to battery life or power.
• Myths of the dumb and stupid. The state of charge of a battery can't be determined by a voltage measurement. The terminal voltage of a battery may stay substantially constant until it is completely discharged. This is another piece of expensive gear called a load tester. And cycles can take up to a day for testing.
PROS:
• Packs can be changed rapidly, they have extended capacity and duration.
• Multiple packs offer continuity, one on the charger while one is in the unit.
• High-production cells or batteries to be combined into a pack. Both voltage and duration may be extended, modified or adjusted for any application.
• Pack holders may be recycled, reducing hazardous waste.
CONS:
• They should not be tampered with.
• It is vitally important to understand there are potential chemical, electrical, and fire risks with the more powerful pack though occurrences are very, very rare.
ENELOOPS and HYBRIDS: CARS and CAMERAS !
• Upgraded by SANYO, as they claim the invention of it, the Eneloop cell is a new second generation of NiMH rechargeable and looks like SANYOS future development. The entire generational difference is in the components such as the chemical and metallurgical makeup of the anodes, reactants and shell, thus less deterioration of the product, (more recharges) loss of energy (self-discharge) and longer shelf life ( better for retailers).
Actually we saw knockoffs in our store show up before the SANYOS got there. Hybrid is a buzz word today. Neither did what it was supposed to.
Combining two types of anything has advantages and disadvantage, but once again the hype usually exceeds the actual conditions experienced. The hybrids we received and I tried them, failed miserably. Some never came alive out of the box. Stay away from them if they do not say SANYO.
TOYOTA and BATTERIES
• The car industry calls it a hybrid because of the popularity of hybrid cars running gas engines combined with NiMH and soon Lithium batteries. Wait till those TOYOTA Prius owners drop in for a new $3000.00 battery, plus installation and diagnostics, and learn the meaning of "going green". The simple act of
the green is going from your wallet to the dealer cashier window.
• As new chemistries come out, there will be change. Electronic devices are rolling over from the Ni-MH platform to Lithium-ion. You might see the BIGGER Lithium's in cars sooner for several reasons. Lithiums are lighter, smaller and stronger "pound for pound". And when production ramps up and fewer plants blow up, prices will come down. Actually the
cost of nickel as in Nickel Metal Hydride has increased threefold in the past few years. China is hoarding it for stainless steel production to keep the pots and pans alive at WAL-MART and IKEA, TARGET and MACY's.
• CAUTION: Lithium-ion batteries are not quit ready for the big show since they have this tendency to "ignite". TRANSLATION: Blow up, burst in flames and secrete some nasty stuff. Just what the Fire Department, our first responders look forward to every time they put a potential car fire out during an accident.
Notice that after the main fire, or thought thereof is quelled they get out the large cable cutters and cut any live connections to the batteries. That could be a 1200 dollar plus cut on a Prius. having worked in the Auto Industry, I can tell you harnesses especially OEM are incredibly expensive.
• I have a bad feeling and a foreboding tendency to think about cable cutting without grounding those tools or heavily insulating the cutters plus lineman type safety gloves.
Llithium-ion batteries in a car application are not quite up to Ni-MH in longevity and that is the key. Make it to the warranty end. For the time being Ni-MH wins.
BACK TO THE ENELOOPS:
• Alkaline's have a longer shelf life, a slow discharge rate and generally produce more shots. This leads to the first promise, "An ENELOOP can deliver five times the amount of pictures in a small camera device". (Small camera device) The older Alkalines could be stored for months or even years without discharge. Thats where stuffing them in the fridge came from. Really dumb idea.
• Rechargeable batteries lose their charge at a high rate while idle. TRUE, SANYO claims it was because was all manufacturers of rechargeable batteries based their sale pitch on higher capacity, and nobody seemed to care about premature ejectulation.
• When Ni-Cad, NiMH and certain Lithium types came along and "they let the recharging begin".
it kind of wiped the alkaline market in digitals. Lots of competition. All kinds of batteries and chargers and more promises. They too have evolved somewhat because they have today higher capacity, longer shelf life. Ni-Cads are almost all gone due to the "toxicity". The FEDS eliminated Ni-Cads period. So we have NiMH and they discharge rather fast sitting on a shelf.
• While regular alkaline batteries will keep their charge for years, the available NiMH batteries had rather a high self discharge rate. So they reinvented the NiMH shell and combined better alchemy in the metals and anodes used. It does make sense. Theoretically the best of both worlds.
• Selling is the art of taking an idea in your brain and putting it into another. Most companies survey customers and look for a problem so they can come up with an answer. SANYO is no different except I am totally sold on how they presented this. "Sanyo was the first company to take on board this 'criticism from the consumers' and developed a rechargeable battery with very low self-discharge". "Heavy starch on the shirts please".
LITHIUM: INFO FROM WIKIPEDIA
The term "lithium battery" refers to a large and growing family of different lithium chemistries, comprising many types of cathodes and electrolytes.
• The main characteristic or most popular form of Lithium in the Commercial/ Industrial applications, or is installed into devices where no consumer replacement is performed is Lithium-thionyl Chloride. It is well suited to extremely low-current applications where long life is necessary, e.g. wireless alarm systems.
• The most common type of lithium cells used in consumer applications use metallic lithium as the anode and manganese dioxide as the cathode, with a salt of lithium dissolved in an organic solvent.
• Lithium promises to be lighter, stronger, more powerful, with no memory and smaller. The voltages with Li-on range in multiples of 3.7. Thus you will see, 3.7 -7.4 - 11.2. outputs which seem strange at times.
• Really futuristic techno-poop terminology abounds when they sell you something that has Lithium based Batteries in it like at Lowes and Home Depot but there is a dark side, especially in tools. They can be unstable at times, poor quality may get mixed with good stuff and they can either burn or explode if not handled properly. Never ever pitch one in a fire.
STANDARDS:
• In the US we are locked in the 6v-12v theology. Our cars are twelve, most emergency lights are six, motorcycles can be both.
• This has existed for decades and was based on 2 volts per cell as used in Sealed Lead Acid. This is commonly known as the US standard. 2v x3 =6 volts and 2v x6 = 12 volts.
• Motorcycles, garden tractors, and other outdoor ATV, water and terrain vehicles can run on six volt setups.
• The most popular being GOLF carts. The standard of the industry relates to heavy usage. Chain six 6 volt batteries together and you have a 36V Golf Cart. Fast with fast recharging. Perfect for golf.
• This will change as Lithium gets more prolific. Thats "Cheaper" in English.
• That's as long as Lithium doesn't continue to blowup plants, pickup trucks and DELL, APPLE Toshiba, Panasonic, and IBM laptop computers can handle the fiery economic loses.
MORE LITHIUM:
There are several other types of
Lithium and we could write a book about the variants. See Wikipedia
on-line encyclopedia, for more information and they have white papers linked on the subject.
NEW FEDERAL AIRLINE
REGULATIONS (LITHIUM):
Effective January 1, 2008,
the following rules apply to the spare lithium batteries you carry with you in
case the battery in a device runs low:
Here are some Points of Lightning. The
problem is Lithium is a fire and explosive hazard. It's hard to fight a fire
below decks in the cargo area, It's easier to contain in the cabin of an
aircraft. Loose Lithium's if jarred or the terminals compromised will burn,
oxidize or explode.
1. Spare batteries are the
batteries you carry separately from the devices they power.
2. When batteries are
installed in a device, they are not considered spare batteries.
3. You may not pack a
spare lithium battery in your checked baggage.
4. You may bring spare
lithium batteries with you in CARRY ON BAGGAGE if you pack them properly. Use
your smarts.
5. Even though we
recommend carrying your devices with you in carry-on baggage as well, if you
must bring one in checked baggage, you may check it with the batteries
installed.
6. Removing batteries from
devices does not enhance safety! When they are in the device they are intended
for they are supported by it's design.
7. Keep batteries in their
original packaging. This packaging is specifically designed to protect
batteries in transportation, at the store, and in your home or worksite.
8. If original packaging
is unavailable, tape over the electrical connections (contacts or terminals)
Electrical tape is great for this job, since if removed promptly will not get gooey. But any adhesive tape not made of
metallic material will do!
9. Placing each battery in
its own individual plastic bag will also isolate the battery's terminals
10. Every rechargeable
battery-powered device comes with a charger that is right for that device. They
do not interchange.
CAUTIONS:
• The Lithium
batteries constructed of Lithium -Ion carry warnings about placing in fire. Li-on
can ignite if exposed to air. In 1995, an entire SONY plant blew up in Japan so
problems with Li-On are not new to SONY. Toshiba was also involved. It is
reported this latest foo-pah will cost about 430 million dollars which has
since doubled.
• IF the small controller
internally should break the battery will short and may explode. People walk in
our local battery store and pitch the dead ones on the counter. Boom. They don't read the sign that says "don't throw batteries, they can explode".
CHEAP IS STUPID:
• Buying cheap Lithium batteries are a stupid
thing to do. Lithium batteries find application in many long-life, critical
devices, such as artificial pacemakers and other implantable electronic medical
devices. These devices use specialized lithium-iodide batteries designed to
last 15 or more years.
• Small lithium batteries are very commonly used in small, portable electronic devices, such as PDAs, watches, thermometers, and calculators, as backup batteries in computers and communication equipment, and in remote car locks. They are available in many shapes and sizes, with a common variety being the 3 volt "coin" type manganese variety, typically 20 mm in diameter and 1.6–4 mm thick.
• The heavy electrical demands of many of these devices make lithium batteries a particularly attractive option. In particular, lithium batteries can easily support the brief, heavy current demands of devices such as digital cameras, and they maintain a higher voltage for a longer period than alkaline cells. The downside is they drop dead instantly when discharged. Little or no warning.
• Lithium batteries can provide extremely high currents and can discharge very rapidly when short-circuited. Although this is useful in applications where high currents are required, a too-rapid discharge of a lithium battery can result in overheating of the battery, rupture, and even explosion.
• Lithium-thionyl chloride batteries are particularly capable of this type of discharge. Consumer batteries usually incorporate over-current or thermal protection or vents in order to prevent explosion. Because of the above risks, shipping and carriage of lithium batteries is restricted in some situations, particularly transport of lithium batteries by air.
• Read the new regulations mandatory January 1, 2008 at the top of the page. The computer industry's drive to increase battery capacity can test the limits of sensitive components such as the membrane separator, a polyethylene or polypropylene film that is only 20-25 μm thick. The energy density of lithium-ion batteries has more than doubled since they were introduced in 1991. When the battery has more and more material, the separator can undergo stress. In French, this translates as "Mon ami, sacre bleu, Oui de poop-e-doo". In English, "Oh Shit" is linguistically correct.
• Unused lithium batteries
provide a convenient source of lithium metal for use as a reducing agent in
illegal methamphetamine labs. Some jurisdictions have passed laws to restrict
lithium battery sales or asked businesses to make voluntary restrictions in an
attempt to help curb the creation of illegal methamphetamine labs.
Ni-MH NIMH is OK for some things, bad for others:
• Ni-MH really gained in
popularity with AA sized cells when Ni-Cadmium went on the federal disposal
list. The world jumped on it especially when Digital came into being. One of the exotic pack builders after Quantum, got caught up in the speed
race with Ni-MH and after a few
Canon flashes became toasters he vanished. Sometimes more is not better and sometimes newer needs a chance to be proven.
1) Don't mix chemistries, types, brands, lots or
capacity of the cells. When you put cells together, you have basically built a
pack. It may store in the camera or flash or it may be in a holder but you made
a pack generally with very POOR connections. Cells should be marked and kept in
specific sets and kept them together for performance to stabilize.
2) Ni-MH
cells do not get better with age, it's the reverse, they actually taper off.
Since Ni-MH tapers and deteriorates as it gets older, the point you have to
change batteries increases or changes.
3) You are kidding yourself if you
believe the life expectancy of the Ni-MH is as promised. We are smart enough to
know not to buy the "Brooklyn Bridge". But, just last week three
idiots bought the water rights under the bridge. Paid Cash too!
4) Ni-MH do not
recharge as many times as professional NiCads. They also have a shelf life no
one talks about. Ni-Cads are actually better in the C and D cell commercial
categories. That's why they are preferred in the higher power packs, the
Ni-Cads and Sealed Lead Acid batteries are the preferred power source for
longer use and less depreciation in professional units.
5) So why the popularity
of NiMH? Simple. It CHEAP and a profit maker. It's cheapest battery to make, least
offensive to the environment, lightweight and it works in all the toys like
phones, beepers, Walkmans, cell-phones, portable phones, and Vibrators.
• Some of you won't like this...batteries come in different price
ranges, qualities and integrities. In batteries simply saying "you get
what you pay for" means nothing. You get what was put inside and NO MORE
THAN what you paid for.
BETTER PRODUCTS COME FROM BETTER COMPONENTS:
BUTTON CELLS AND CAMERA OWNERS:
There are batteries, so small I have pills I take that are larger. Not too common anymore after being around for the longest time but folks still seem to use them in older smaller or high end cameras like Leica's they just won't part with. I don't blame them. They are available in a variety of chemistries.
The earliest button cells were the mercury type. They produced from 1.35 to 1.4 volts per cell, depending on the model. These are, no longer available for ecological reasons.
• Replacements: PLAN A - Silver oxide button cells deliver about 1.55 volts per cell and can provide more total energy than alkaline cells. Using these cells in most cameras designed for mercury cells can cause exposure inaccuracies unless you have the meter re-calibrated; Est Cost 70.00 to 90.00 most cameras.
• Replacements: PLAN B - Zinc-air cells, made by Wein Products may be found at any Radio Shack or drug store. They put out 1.35 volts per cell, politically correct and fairly cheap. They rely on oxygen from the air to generate electricity. The bad part is life cycle. Poor, possibly going dead in months. Change them every ninety days.
• Replacements: PLAN C The other mercury replacement I tested under
the same conditions was the MR-9 adapter distributed by C.R.I.S Camera Services. This device consists
of a metal cup into which you place a 76 silver-oxide cell such as a Varta
V76PX. The MR-9 contains a small circuit that drops the battery’s 1.55 volts to
a nominal 1.30 volts. It worked as advertised and gave comparable results to the V76PX in all tests.
• The bottom line: A very occasional
vintage camera user would be likely to get better service from the MR9, while
the heavy shooter may find the Wein Cells more cost-effective. You can get information on the MR9 on
the C.R.I.S web site
www.criscam.com, where the adapter can also be
ordered. The price is $29.95 plus shipping and handling. A silver 76 cell from
the same source is $2.90. Their phone number is (800) 216-7579.
DEAD TRUTH ABOUT FLASHES AND BATTERIES:
Batteries
may be thought of as temporary storage devices that are categorically sorted by
their chemistry or type, size or shape, single throw away use or rechargeable.
In addition, they are valued by capacity and quality. From my understanding too
often I hear “what’s the best price”, never “who has got the best quality”.
It’s just human nature since all batteries are created equal. WRONG
Single usage discard
may be: Lithium, Alkaline, Zinc
Reusable batteries may be: Ni-Cad, Nickel Metal Hydride, Sealed Lead Acid, Lithium-Ion
The TEN COMMANDMENTS OF BATTERY CARE:
• Fully charge a new battery before use to get rid of
the storage blues.
• Never run any battery to exhaustion. You might have to kick
start the battery to kick start what ever you were starting.
• Good chargers are not the fastest chargers. They are battery
killers.
• Don't mix
rechargeable cells that are not from the same brand, much less the same batch,
much less the same size or capacity.
• Do not store batteries in the fridge, you’ll rust and split the cases which
are not made from stainless.
• Mixing cells of different capacities can cause permanent
damage to the weakest one in the set.
• Different manufacturers state a cell’s capacity at anywhere from a ten-hour
to a three-hour discharge rate. You shouldn’t simply assume that all 2000 MAH
capacity cells will perform identically in your gear.
• Don't leave your batteries in the
charger for weeks on end unless the charger is specifically designed to handle
the maintenance charge curve.
• Put cool batteries in a flash only , never hot or warm cells from a charger
into your flash.
• Read the instructions. And don’t believe half the hype.What is a Battery?
MORE ON BATTERIES:
A device usually referred to as an electrochemical device that converts
chemical energy into electricity, by use of a galvanic cell. A galvanic cell is
composed of two electrodes (an anode and a cathode) and an electrolyte
solution. Placing these cell in
packs or strings create different voltages. That’s why we call them battery
Packs. Batteries store energy they do not make it. Rechargeable batteries can
be restored many times. Batteries are not 100% efficient, energy is lost as
heat and chemical reactions occur as when charging and discharging. Typical
efficiency in a lead-acid battery is 85-95%, in alkaline and NiCad battery it
is about 65%.
The
Battery Killer-Sulfation-?
Sulfation is the formation or deposit of lead sulfate on the surface and in the
pores of the lead plates. If the sulfation becomes excessive, the battery may
not work at all. Sulfation is caused by stored a long time in a discharged
condition, operating at excessive temperatures, and prolonged under or over
charging.
What
are some of the major applications for lead acid batteries?
The major applications for lead acid batteries are automotive, related marine,
and deep-cycle. Deep-cycle includes solar electric (PV), backup power, and RV
and electric motor applications like trolling motors. Their life depends on how
it is used, how it is maintained and charged, temperature, and other factors.
SEALED LEAD ACID BATTERIES:
• Flooded or wet cells. Flooded may be standard, with removable caps, or the so-called "maintenance free".
• Gelled, as in Sonnenshine from Germany All gelled are sealed and a few are "valve regulated", which means that a tiny valve keeps a slight positive pressure. Nearly all AGM batteries are sealed valve regulated (commonly referred to as "VRLA" - Valve Regulated Lead-Acid).
• AGM (Absorbed Glass Mat). AGM batteries are also sometimes called "starved electrolyte" or "dry", because the fiberglass matying is only 95% saturated with Sulfuric acid and there is no excess liquid.
What is a Sealed
Maintenance Free Battery?
Sealed batteries are known as maintenance free batteries. They are made with
vents that (usually) cannot be removed..
How does an
AGM battery differ from a Gel cell?
The sealed non-spillable maintenance free valve regulated battery uses
"Absorbed Glass Mats", or separators between the plates. This is a
very fine fiber Boron-Silicate glass mat. These type of batteries have the
advantages of gelled, but can take much more abuse. A GEL battery design is typically a modification of a standard battery
with a gelling agent added to the electrolyte to reduce movement inside the
battery case.
RATINGS:
What is the Amp Hour (Ah) rating? It is amps X hours. Example: An amp-hour is one amp for one hour or 20 amps for
five minutes (20th of an hour). The accepted AH rating time period
for batteries used in backup power systems (and for nearly all deep cycle
batteries) is the "20 hour rate".
What is a MilliAmp Hour (MAH)?
MilliAmp Hour means how much current a battery will discharge over a period of
one hour. Higher numbers here reflect a long battery runtime and or higher
storage capacity. Higher MAH ratings do not necessarily reflect on speed but
more on runtime.

